Tungsten, 2023-06, Vol.5 (2), p.270-276
2023
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- Autor(en) / Beteiligte
- Titel
- A bi-As-capped and tetra-V-substituted arsenomolybdate: synthesis, structure, capacitive and electrocatalytic properties
- Ist Teil von
- Tungsten, 2023-06, Vol.5 (2), p.270-276
- Ort / Verlag
- Singapore: Springer Nature Singapore
- Erscheinungsjahr
- 2023
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- A bi-As-capped and tetra-V-substituted arsenomolybdate (Hbib) 2 (biyb) 3 [As III 2 As V Mo VI 8 V V 4 O 40 ] 2 ·H 2 O ( 1 ) (bib = 1.4-Bis(imidazoly)butane; biyb = 1,4-bis(imidazol- 1-ylmethyl)benzene) has been constructed through hydrothermal methods and characterized by conventional method. Compound 1 is a tetra-V substituted {AsMo VI 8 V V 4 O 4 } polyanions capped by two As III cations at two symmetrical ditch in {AsO 4 } rectangular pyramid geometry. It exhibits higher specific capacitance, capacitance retention, and electrocatalytic activities for oxidizing ascorbic acid and reducing peroxide hydrogen.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 2661-8028eISSN: 2661-8036DOI: 10.1007/s42864-023-00205-5Titel-ID: cdi_proquest_journals_2921194896
- Format
- –
- Schlagworte
- Arsenic, Ascorbic acid, Benzene, Capacitance, Carbon, Chemistry and Materials Science, Crystal structure, Electrodes, Electrons, Energy storage, Fourier transforms, Ligands, Materials Engineering, Materials Science, Metallic Materials, Nuclear Chemistry, Original Paper, Oxidation, Particle and Nuclear Physics, Polyelectrolytes, Spectrum analysis, Substitutes