Details

Autor(en) / Beteiligte

• Obrezkova, M. A.
• Kalinina, A. A.
• Pavlichenko, I. V.
• Vasilenko, N. G.
• Mironova, M. V.
• Semakov, A. V.
• Kulichikhin, V. G.
• Buzin, M. I.
• Muzafarov, A. M.

Titel

Comb-Like Polymethylsiloxanes. Synthesis, Structure and Properties

Ist Teil von

• SILICON, 2015-04, Vol.7 (2), p.177-189

Ort / Verlag

Dordrecht: Springer Netherlands

Erscheinungsjahr

2015

Quelle

SpringerLink

Beschreibungen/Notizen

• Comb-like polymethylsiloxanes consisting of a silsesquioxane backbone and dimethylsiloxane side chains were synthesized by means of the “grafting to” method using a linear polyfunctional matrix [SiMe(ONa)O] n and monofunctional oligomers (CH 3 ) 3 Si[OSi(CH 3 ) 2 ] n OCOCH 3 . The effects of architecture of the synthesized methylsiloxane polymers on their physicochemical properties, rheology, and behavior at the air–water interface were studied and compared with those for the linear analogue – polydimethylsiloxane.