Details

Autor(en) / Beteiligte

• Zhan, CaiHong
• Cai, WenXuan
• Feng, YunLong
• He, YinHua

Titel

An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration

Ist Teil von

• Science China Chemistry, 2010-06, Vol.53 (6), p.1261-1265

Ort / Verlag

Heidelberg: SP Science China Press

Erscheinungsjahr

2010

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A dicarboxylate ligand, 5-carboxyl-1-carboxymethyl-2-oxidopyridinium (H 2 L), was utilized to form four complexes with the general formula [M(HL) 2 (H 2 O)]·2H 2 O, M = Cu II (1), Zn II (2), MnII (3), Cd II (4). The crystals were isomorphous, belonging to the monoclinic C2/c space group. They were constructed from 1D chains and further linked by hydrogen bonds into a novel binodal (6,8)-connected 3D supramolecular network with twofold self-penetration. Photoluminescence studies revealed that complexes 2–4 displayed intense structure-related fluorescent emission bands.