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Incorporation of Transition Metal Ions into Li2O + LiF + ZnF2 + B2O3 + P2O5-MnO Glasses: Effects on Elastic, Mechanical, and Radiation Effectiveness Behaviors
Ist Teil von
Journal of electronic materials, 2024, Vol.53 (1), p.462-472
Ort / Verlag
New York: Springer US
Erscheinungsjahr
2024
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The desired target of the current report was to examine the efficiency of MnO-based glass systems against x- or g-rays, and mechanical properties with varying amounts of MnO incorporation. The focus was on evaluating their radiation shielding performance and determining their elasto-mechanic intrinsic characteristics. Various gamma and neutron shielding factors, including HVL (half-value layer),
Z
eff
(
Z
eff
: effective atomic number),
Z
eq
(equivalent atomic number), EBF (exposure buildup factor), EABF (energy absorption buildup factor), ACS (atomic cross-section), ESC (electronic cross-section), and SAFE
*
(specific absorbed fraction of energy) were planned to assess the radio-protection capabilities of the probed glass systems. Exemplified at
E
= 15 keV, the MAC (mass attenuation coefficient) values are: 13.99 cm
2
/g, 14.03 cm
2
/g, 14.18 cm
2
/g, 14.36 cm
2
/g, and 14.55 cm
2
/g for the glass blocks encoded as LZBP, 0.1Mn:LZBP, 0.5Mn:LZBP, 1.0Mn:LZBP, and 1.5Mn:LZBP respectively, while the SAFE values vary between 31907 g
−1
and 32013 g
−1
as Mn
2+
is increased from 0.0 mol% to 1.5 mol%. The outcomes indicate that as the manganese (II) oxide mol% increases, then the MAC,
Z
eff
,
Z
eq
, ACS, and ESC values also increase. Among the samples, 1.5Mn:LZBP exhibited the least HVL, EBF, EABF, and SAFE values. This glass, which contains 1.5 mol% of MnO and has the highest interconnecting bonding/volume, may be deemed as an advanced glass for ray protection in the different fields, providing valuable insights into their radiation shielding performance.