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Specific Features of Concentration Quenching of the Fe2+ Luminescence in a ZnSe Single Crystal
Ist Teil von
Bulletin of the Lebedev Physics Institute, 2023-12, Vol.50 (Suppl 9), p.S1006-S1014
Ort / Verlag
Moscow: Pleiades Publishing
Erscheinungsjahr
2023
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The time dependence of the luminescence power of the Fe
2+
ion in ZnSe at liquid nitrogen temperature has been investigated where it is excited by a short laser pulse with a wavelength of 2940 nm at various concentrations of Fe
2+
ions and various pulse energy density on the sample surface. The shape of the luminescence decay curve is shown to depend both on the Fe
2+
concentration and on the laser pulse energy density. This behavior of luminescence kinetics was interpreted as a manifestation of concentration quenching of the Fe
2+
excited state. A theoretical description of the observed dependences is proposed, the best agreement between calculated and experimental curves being obtained if we assume that the probability of quenching per time unit is proportional to the square of the concentration of Fe
2+
ions in the excited state.