Details

Autor(en) / Beteiligte

• Wang, Zepan
• Wu, Peiyuan
• Zou, Xubing
• Wang, Sheng
• Du, Lei
• Ouyang, Ting
• Liu, Zhao‐Qing

Titel

Optimizing the Oxygen‐Catalytic Performance of Zn–Mn–Co Spinel by Regulating the Bond Competition at Octahedral Sites

Ist Teil von

• Advanced functional materials, 2023-04, Vol.33 (16), p.n/a

Ort / Verlag

Hoboken: Wiley Subscription Services, Inc

Erscheinungsjahr

2023

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• By using the more electro‐negative Mn3+ ion to partially replace Co3+ at the octahedral site of spinel ZnCo2O4, i.e., forming ternary Zn–Mn–Co spinel oxide, the electrocatalytic oxygen reduction/evolution activity is found to be significantly increased. Considering the physical characterization and theoretical calculations, it demonstrated that the bond competition played a key role in regulating the cobalt valence state and the electrocatalytic activity. The partial replacement of octahedral‐site‐occupied Co3+ by Mn3+ can effectively modulate the adjacent Co–O bond and induce the Jahn–Teller effect, thus changing the originally stable crystal structure and optimizing the binding strength between the active center and reaction intermediates. Certainly, the Mn‐substituted ZnMn1.4Co0.6O4/NCNTs exhibit higher electrocatalytic oxygen reduction reaction (ORR) activity than that of ZnCo2O4/NCNTs and ZnMn2O4/NCNTs, supporting that the Co–O bond covalency determines the ORR activity of spinel ZnCo2O4. This study offers the competition between adjacent Co–O and Mn–O bonds via the BOh–O–BOh edge‐sharing geometry. The ion substitution at octahedral sites by less electronegative cations can be a new and effective way to improve the electrocatalytic performance of cobalt‐based spinel oxides. The excellent electrocatalytic performance of ZnMn1.4Co0.6O4/NCNTs for oxygen reduction reaction is verified, presenting significant power density and durability in Zn–air batteries. A bond competition mechanism for the octahedral sites of spinel is also proposed. The presence of bond competition between CoO and MnO enables to modulate and optimize the electronic structure of ZnMn1.4Co0.6O4, resulting in the superior electrocatalytic activity.