Details

Autor(en) / Beteiligte

• Merkes, Jean Michel
• Raabe, Gerhard
• Kiessling, Fabian
• Rueping, Magnus
• Banala, Srinivas

Titel

An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe

Ist Teil von

• Advanced optical materials, 2023-03, Vol.11 (6), p.n/a

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2023

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• The isolation and characterization of a kinetically stable oxadiazaborinine (ODB) dye are described, which undergoes an unexpected thermal boron rearrangement with a color change and increase in fluorescence. This controllable reaction allows for the use as a practical time‐temperature indicator probe with the advantages of photostability, non‐reversibility, and environmental friendliness. The novel oxadiazaborinin dye described here undergoes a temperature and solvent‐dependent, irreversible O‐ to N‐ rearrangement of the BF2 group or a cleavage of BF2 and acetyl groups, accompanied by a change in color and fluorescence. These changes can be used to quantify the integrated temperature fluctuations of cold‐chain logistics of perishable products.