Journal of materials science, 2023-03, Vol.58 (9), p.3909-3919
2023
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- Autor(en) / Beteiligte
- Titel
- Microstructure and electrical properties of barium cerate thin films
- Ist Teil von
- Journal of materials science, 2023-03, Vol.58 (9), p.3909-3919
- Ort / Verlag
- New York: Springer US
- Erscheinungsjahr
- 2023
- Quelle
- SpringerNature Journals
- Beschreibungen/Notizen
- Single-phase barium cerate films of 1.5 µm thickness were deposited using an e-beam physical vapor deposition method and studied using X-ray diffractometry, scanning electron microscopy, and impedance spectroscopy. The films deposited on the Inconel 600, MgO, YSZ, and Al 2 O 3 substrates at 500–700 °C differed in morphology, grain sizes, crystallographic orientation, and electrical properties. The mechanism of film growth was found to depend on the substrate and deposition temperature. The films on metallic substrates require a lower temperature to form a single-phase barium cerate phase. The values and activation energy of conductivity were found to depend mainly on the film microstructure, in particular on the crystallographic orientation of grains. The relaxation of strained films causes a decrease in conductivity.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0022-2461eISSN: 1573-4803DOI: 10.1007/s10853-023-08297-7Titel-ID: cdi_proquest_journals_2780257977
- Format
- –
- Schlagworte
- Activation energy, Aluminum oxide, Analysis, Barium, Ceramics, Characterization and Evaluation of Materials, Chemistry and Materials Science, Classical Mechanics, Conductivity, Crystallography, Crystallography and Scattering Methods, Electric properties, Electrical properties, Electron beams, Film growth, Grain size, Heat resistant alloys, Materials Science, Microstructure, Misfit dislocations, Nickel alloys, Phase transitions, Physical vapor deposition, Point defects, Polymer Sciences, Solid Mechanics, Spectrum analysis, Substrates, Thin films, Yttria-stabilized zirconia