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Development of a Novel, Impurity-Scavenging, Corrosion-Resistant Coating for Ni-Based Superalloy CMSX-4
Ist Teil von
High temperature corrosion of materials, 2023-02, Vol.99 (1-2), p.3-13
Ort / Verlag
New York: Springer Nature B.V
Erscheinungsjahr
2023
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Abstract
Sulfur, a common impurity arising from atmospheric and environmental contamination, is highly corrosive and detrimental to the lifespan of nickel superalloys in jet engines. However, sulfur-scavenging coatings have yet to be explored. Our study presents the successful development of a stable, uniform, impurity-scavenging Ni-Mn coating on Ni-based superalloy CMSX-4, through electroplating. The coating was characterised via combined scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy. An optimal coating thickness of > 600 nm was deposited. The coated alloy was exposed to corrosive salt mixture 98% Na
2
SO
4
–2% NaCl at 550 °C for 100 h, mimicking engine exposure conditions, thereby proving that the coating successfully trapped sulfur and prevented its diffusion into an underlying alloy. This work presents a promising development for the prevention of sulfur-induced corrosion in industrial setting such as gas turbine engine, where the effects of sulfur diffusion into the bulk alloy could lead to premature failure.
Graphical Abstract