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Doping Heptagon‐Containing π‐Conjugated Systems with Boron
Ist Teil von
European journal of organic chemistry, 2022-12, Vol.2022 (47), p.n/a
Ort / Verlag
Weinheim: Wiley Subscription Services, Inc
Erscheinungsjahr
2022
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
As the models for studying defected graphene, π‐conjugated systems containing heptagonal rings have attracted increasing interest due to their dynamic behaviors, electronic properties, aromaticity, and solid‐state packing. Doping heptagon‐containing π‐conjugated systems with boron not only makes π‐conjugated systems with the boron‐doped heptagonal ring have structural similarity to their all‐carbon analogues, but also could significantly change their electronic properties and intermolecular interactions. This review summarizes research on the different synthetic routes to access boron‐doped heptagons including borepins, azaborepins, and oxaborepins, with the emphasis on the structure‐property relationships at the molecular level.
This review summarizes research on the different synthetic routes to access boron‐doped heptagons including borepins, azaborepins, and oxaborepins, with the emphasis on the structure‐property relationships at the molecular level.