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The energy crisis is one of the most emergency problems that humanity is facing now. To alleviate energy crisis, some new energy sources different from traditional fossil energy are developed in the past decades, for example, nuclear energy, wind energy, solar energy, et al. Among these new energy sources, an important energy existing in the ocean and river named as salinity gradient energy benefits from the features of green, safe, low cost and huge amount, and comes into the researcher’s sight. In this article, we review the recent progress in harvesting salinity gradient energy with reverse electrodialysis (RED) membrane. First, the mechanism of RED was introduced, including the basic structure and working principle of RED, the ion selectivity, and the ion rectification effect. The materials which are suitable for RED were discussed in detail, such as 1D nanofluidic nanochannels, 2D materials, and composite materials. Among these materials, 2D materials are thought to be one kind of powerful material for RED because of the feasibility of producing ion-selective membranes. Besides, we dwell on the influences of solution conditions on the RED performance, like the salt gradient and species, pH value, and so on. Finally, we discussed what the RED membranes need in theory and experiment to satisfy the practical application. And the large-scale production and the anti-fouling for the long-term running of RED membranes are two key issues needed to be solved through the analysis of this paper.