Details

Autor(en) / Beteiligte

• Zhao, Tingwen
• Wang, Shuhao
• Li, Yibing
• Jia, Chen
• Su, Zhen
• Hao, Derek
• Ni, Bing‐jie
• Zhang, Qiang
• Zhao, Chuan

Titel

Heterostructured V‐Doped Ni2P/Ni12P5 Electrocatalysts for Hydrogen Evolution in Anion Exchange Membrane Water Electrolyzers

Ist Teil von

• Small (Weinheim an der Bergstrasse, Germany), 2022-10, Vol.18 (40), p.n/a

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2022

Quelle

Wiley Online Library All Journals

Beschreibungen/Notizen

• Regulating the electronic structure and intrinsic activity of catalysts’ active sites with optimal hydrogen intermediates adsorption is crucial to enhancing the hydrogen evolution reaction (HER) in alkaline media. Herein, a heterostructured V‐doped Ni2P/Ni12P5 (V–Ni2P/Ni12P5) electrocatalyst is  fabricated through a hydrothermal treatment and controllable phosphidation process. In comparison with pure‐phase V–Ni2P, in/ex situ characterizations and theoretical calculations reveal a redistribution of electrons and active sites in V–Ni2P/Ni12P5 due to the V doping and heterointerfaces effect. The strong coupling between Ni2P and Ni12P5 at the interface leads to an increased electron density at interfacial Ni sites while depleting at P sites, with V‐doping further promoting the electron accumulation at Ni sites. This is accompanied by the change of active sites from the anionic P sites to the interfacial Ni–V bridge sites in V–Ni2P/Ni12P5. Benefiting from the interface electronic structure, increased number of active sites, and optimized H‐adsorption energy, the V‐Ni2P/Ni12P5 exhibits an overpotential of 62 mV to deliver 10 mA cm–2 and excellent long‐term stability for HER. The V–Ni2P/Ni12P5 catalyst is applied for anion exchange membrane water electrolysis to deliver superior performance with a current density of 500 mA cm–2 at a cell voltage of 1.79 V and excellent durability. Rationally designed V‐doped Ni2P/Ni12P5 heterostructured electrocatalysts are presented by taking advantage of heterointerfaces and heteroatom doping, demonstrating excellent catalytic performance and stability for the hydrogen evolution reaction in alkaline electrolyte and anion exchange membrane water electrolyzer applications, thanks to the optimized electronic structure and abundant heterointerfaces.