Details

Autor(en) / Beteiligte

• Zhang, Liling
• Dai, Gui
• Yu, Shoufu
• Ma, Chengjian
• Dai, Hailu
• Bi, Lei

Titel

BaTb0.3Fe0.7O3−δ: a new proton-conductor-derived cathode for proton-conducting solid oxide fuel cells

Ist Teil von

• Sustainable energy & fuels, 2022-07, Vol.6 (19), p.4375-4382

Ort / Verlag

London: Royal Society of Chemistry

Erscheinungsjahr

2022

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• BaTbO3 is a much less focused proton-conductor than the traditional BaCeO3–BaZrO3 system due to its lower proton conductivity. However, the present study reveals that using BaTbO3 as the parent material to form the new BaTb0.3Fe0.7O3−δ (BTF) can boost the cathode performance for proton-conducting solid oxide fuel cells (H–SOFCs). Compared with the traditional Fe-doped BaZrO3 (BZF), the electronic structure of BTF is regulated due to the presence of Tb3+ and Tb4+, leading to more abundant oxygen vacancies and improved oxygen reduction reaction activities compared with BZF, which have been demonstrated by both experiments and first-principles calculations. The slightly decreased proton diffusion by using BaTbO3 compared with BaZrO3 is compensated by the greatly enhanced oxygen diffusion and surface exchange abilities, leading to a record-high performance for the BTF cathode compared with other proton conductor-derived cathodes for H–SOFCs.