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AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX
Ist Teil von
Journal of structural chemistry, 2022-08, Vol.63 (8), p.1262-1273
Ort / Verlag
Moscow: Pleiades Publishing
Erscheinungsjahr
2022
Quelle
SpringerNature Journals
Beschreibungen/Notizen
The reaction of Co(OAc)
2
·4H
2
O with multisite coordinated salamo-based ligand H
2
L containning six coordinating sites in presence of co-ligand NCS
–
anions afforded successfully a trinuclear Co(II) complex [Co
3
(L)
2
(NCS)
2
]. The trinuclear Co(II) complex has been characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopic methods and DFT calculation. In addition, the structure of the Co(II) complex has been confirmed by single crystal X-ray crystallography. X-ray crystal structure analysis of the Co(II) complex revealed that the Co(II) complex consists of three Co(II) atoms coordinated by two fully deprotonated ligand (L)
2–
units and co-ligand NCS
–
anions. The close surveillance of the crystal structure of the Co(II) complex discloses some notable non-covalent interactions like H-bonding, C-H⋯π and π⋯π. The luminescent property of the Co(II) complex has been studied in methanol solution. Apart from, as a complementary revelation, intermolecular interactions with respect to percentages of hydrogen bondings in the X-ray crystal structure of the trinuclear Co(II) complex was quantified by analyses of Hirshfeld surfaces and fingerprint plots.