Details

Autor(en) / Beteiligte

• Li, Yue
• Wang, Yutong
• Fan, Weidong
• Sun, Daofeng

Titel

Flexible metal-organic frameworks for gas storage and separation

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2022-03, Vol.51 (12), p.468-4618

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2022

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Flexible metal-organic frameworks (MOFs) have gradually attracted much attention due to their reversible structural changes and flexible structural responses. The basic research of flexible MOFs is to study their dynamic responses under different external stimuli and translate the responses into applications. Most research studies on flexible MOFs focus on gas storage and separation, but lack a systematic summary. Here, we review the development of flexible MOFs, the structural transformation under the external effects of temperature, pressure, and guest molecules, and their applications in gas storage and separation. Microporous MOFs with flexible structures provide unique opportunities for fine-tuning their performance because the pore shape and size can be controlled by external stimuli. The characteristics of breathing phenomena and large specific surface area make flexible MOFs suitable candidates for gas storage and separation. Finally, the application prospects of flexible MOFs are reported. Dynamic response of flexible MOF for gas storage and separation.