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Growth defects in GeSn/Ge/Si(001) epitaxial layers grown by hot wire chemical vapor deposition of Ge with co-evaporation of Sn
Ist Teil von
Journal of crystal growth, 2022-01, Vol.578, p.126421, Article 126421
Ort / Verlag
Amsterdam: Elsevier B.V
Erscheinungsjahr
2022
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
•GeSn/Ge/Si(001) epitaxial layers were grown by hot wire chemical vapor deposition.•Nucleation of α-Sn particles is main mechanism of strain relaxation in GeSn layers.•β-Sn islands forming on GeSn layers due to Sn segregation were identified by CRM.
We report on the investigation of the growth defect formation in the GeSn/Ge/Si(001) epitaxial layers grown by hot wire chemical vapor deposition of Ge with simultaneous co-evaporation of Sn from an effusion cell. The nucleation of α-Sn nanoinclusions in the course of the growth process was found to be the main mechanism of elastic strain relaxation in the Ge1-xSnx epitaxial layers at x>2.5% as opposed to the misfit dislocation formation at the GeSn/Ge interfaces. Also, β-Sn nanoislands nucleating on the surface of the GeSn epitaxial layers with increased Sn concentration due to Sn segregation were identified by confocal Raman microscopy.