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Successive magnetic transitions with large refrigerant capacity in arc-melted Mn3−xFexSn2 (x = 0.3, 0.7) alloys
Ist Teil von
Journal of magnetism and magnetic materials, 2022-01, Vol.541, p.1, Article 168466
Ort / Verlag
Amsterdam: Elsevier B.V
Erscheinungsjahr
2022
Quelle
ScienceDirect
Beschreibungen/Notizen
This work investigates the magneto-caloric effect and critical behavior in Mn3−xFexSn2 (x = 0.3, 0.7) alloys synthesized by arc melting method. The alloys show two successive second order magnetic phase transitions at TC1≈ 254 K (261 K) and TC2≈ 205 K (185 K), respectively for x = 0.3 (0.7). The modified Arrot plot study around paramagnetic–ferromagnetic transition at TC1 reveals the critical exponent, β = 0.397 (0.378) with long-range of magnetic interactions for x = 0.3 (0.7). Importantly, the magneto-caloric study for x = 0.3 (0.7) gives large refrigerant capacity (RC) of 330 (250) J/kg at 5 T applied magnetic field. The large RC value and two successive magnetic transitions makes these earth abundant-based Mn3−xFexSn2 alloys highly promising for magnetic refrigeration in a wide temperature span.
•Pnma type Mn3−xFexSn2 (x = 0.3, 0.7) alloys are firstly successively synthesized by arc melting method.•The critical exponents are confirmed by various methods and found in agreement with each other.•Critical exponent study reveal the long-range of magnetic interactions for alloys.•The refrigerant capacity (RC) is significant for refrigerant applications in wide temperature range.