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Effect of Cobalt on Microwave Sintered Pb1-xCoxFe12O19 (x=0.25, 0.50 and 0.75) Nanoparticles: Structural and Dielectric Studies
Ist Teil von
Journal of electronic materials, 2021-12, Vol.50 (12), p.7005-7016
Ort / Verlag
New York: Springer US
Erscheinungsjahr
2021
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Pb
1-x
Co
x
Fe
12
O
19
nano-crystallites with an average crystal diameter varying between 74 and 86 nm are prepared via sol-gel auto-combustion. The X-ray diffraction (XRD) studies confirmed the single-phase P63/mmc space group. The surface morphology of the samples carried out using a field emission scanning electron microscope (FESEM) revealed the long hexagonal structure of the ferrites. Dielectric characterization is studied from room temperature to 800 K and in the frequency range of 100 Hz to 5 MHz. The ferrites exhibited two transition peaks in this temperature region which are attributed to phase transitions between ferroelectric to anti-ferroelectric and anti-ferroelectric to paraelectric phase. The composition
x
= 0.75 is suitable for high definition television deflection yokes for it has exhibited the highest dielectric constant, low ac electrical conductivity.
Graphic Abstract