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Ruthenium-catalyzed N -alkylation of amino-1,3,5-triazines using alcohols
Ist Teil von
New journal of chemistry, 2021-09, Vol.45 (35), p.15776-15779
Ort / Verlag
Cambridge: Royal Society of Chemistry
Erscheinungsjahr
2021
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
An efficient ruthenium-catalyzed
N
-alkylation of amino 1,3,5-triazines with alcohols was achieved
via
a BH/HA strategy. Following this simple, facile, and high atom economical protocol, a broad range of products was prepared in moderate to good yields and heterocyclic or benzylic alcohols containing various functionalities were tolerated. The application of the reaction is also further demonstrated by the synthesis of alkylated secondary amine-1,3,5-triazines from olefinated amino-1,3,5-triazines and alcohols
via
a one pot
N
-alkylation and reductive reactions.