Details

Autor(en) / Beteiligte

• Yan, Rui
• Ma, Tian
• Cheng, Menghao
• Tao, Xuefeng
• Yang, Zhao
• Ran, Fen
• Li, Shuang
• Yin, Bo
• Cheng, Chong
• Yang, Wei

Titel

Metal–Organic‐Framework‐Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries

Ist Teil von

• Advanced materials (Weinheim), 2021-07, Vol.33 (27), p.n/a

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2021

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Metal‐sulfur batteries (MSBs) are considered up‐and‐coming future‐generation energy storage systems because of their prominent theoretical energy density. However, the practical applications of MSBs are still hampered by several critical challenges, i.e., the shuttle effects, sluggish redox kinetics, and low conductivity of sulfur species. Recently, benefiting from the high surface area, regulated networks, molecular/atomic‐level reactive sites, the metal‐organic frameworks (MOFs)‐derived nanostructures have emerged as efficient and durable multifaceted electrodes in MSBs. Herein, a timely review is presented on recent advancements in designing MOF‐derived electrodes, including fabricating strategies, composition management, topography control, and electrochemical performance assessment. Particularly, the inherent charge transfer, intrinsic polysulfide immobilization, and catalytic conversion on designing and engineering of MOF nanostructures for efficient MSBs are systematically discussed. In the end, the essence of how MOFs’ nanostructures influence their electrochemical properties in MSBs and conclude the future tendencies regarding the construction of MOF‐derived electrodes in MSBs is exposed. It is believed that this progress review will provide significant experimental/theoretical guidance in designing and understanding the MOF‐derived nanostructures as multifaceted electrodes, thus offering promising orientations for the future development of fast‐kinetic and robust MSBs in broad energy fields. Recent advancements in designing metal–organic framework (MOF)‐derived nanostructures for multifaceted electrodes in metal–sulfur batteries (MSBs) are presented. Particularly, the inherent charge transfer, polysulfides immobilization and conversion, and morphology–property correlations for MSB applications are systematically discussed. The future tendencies regarding the construction of MOF‐derived nanostructures are also summarized, which will provide experimental/theoretical guidance in developing fast‐kinetic and robust MSBs.