Details

Autor(en) / Beteiligte

• Usol’tsev, A. N.
• Sokolov, M. N.
• Fedin, V. P.
• Adonin, S. A.

Titel

Bi- and Tetranuclear Antimony(III) Bromide Complexes with Alkanediyl-bis(3-methylpyridinium) Cations

Ist Teil von

• Russian journal of inorganic chemistry, 2021-06, Vol.66 (6), p.827-833

Ort / Verlag

Moscow: Pleiades Publishing

Erscheinungsjahr

2021

Quelle

springer (창간호~2014)

Beschreibungen/Notizen

• Polynuclear bromoantimonates(III) with alkanediyl-bis(3-methylpyridinium) cations (3-MePy )—(3-MePyC 2 ) 3 [Sb 2 Br 9 ] 2 ( 1 ), (3-MePyC 3 ) 2 [β-Sb 4 Br 16 ] ( 2 ), and (3-MePyC 4 ) 2 [α-Sb 4 Br 16 ] ( 3 )—and bromobismuthate(III) (3-MePyC 3 ) 3 [Bi 2 Br 9 ] 2 ( 4 ) have been synthesized by reacting solutions of Sb 2 O 3 (Bi 2 O 3 ) in HBr with bromides of the corresponding organic cations. Differences in the structure between compounds 1 – 3 and bromobismuthates with analogous cations ( 4 and previously studied compounds) have been considered.