Organic chemistry frontiers an international journal of organic chemistry, 2021-06, Vol.8 (11), p.2576-2582
2021
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Details
- Autor(en) / Beteiligte
- Titel
- Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: stereo-controlled assembly and catalysis
- Ist Teil von
- Organic chemistry frontiers an international journal of organic chemistry, 2021-06, Vol.8 (11), p.2576-2582
- Ort / Verlag
- London: Royal Society of Chemistry
- Erscheinungsjahr
- 2021
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- By varying the metal/ligand ratio, either dinuclear triple helicates (ΛΛ/ΔΔ-La2LR/S3) or mononuclear pincer complexes (Λ/Δ-LaLR/S) can be stereo-selectively obtained from the same chiral bis-tridentate ligand (LR/S). Due to the open metal sites available in both complexes, their catalytic properties have been demonstrated with the asymmetric Friedel–Crafts alkylation reactions.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 2052-4110eISSN: 2052-4129DOI: 10.1039/d1qo00369kTitel-ID: cdi_proquest_journals_2534998176
- Format
- –
- Schlagworte
- Alkylation, Catalysis, Coordination compounds, Crystallography, Ligands, Organic chemistry