Details

Autor(en) / Beteiligte

• Joy, Md Tuhinur R.
• Ghosh, Shishir
• Kabir, Shariff E.

Titel

Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS‒SnPh3 (pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

Ist Teil von

• Journal of chemical crystallography, 2021-06, Vol.51 (2), p.257-264

Ort / Verlag

New York: Springer US

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Reactivity of pymS‒SnPh 3 (pymS = pyrimidine-2-thiolate) towards two unsaturated triosmium clusters [Os 3 (CO) 10 (μ-H) 2 ] and [Os 3 (CO) 8 {µ 3 -Ph 2 PCH 2 P(Ph)C 6 H 4 }(μ-H)] are investigated. Reaction of pymS‒SnPh 3 with [Os 3 (CO) 10 (μ-H) 2 ] affords [Os 3 (CO) 10 (µ-pymS)(µ-H)] ( 1 ) and [Os 3 (CO) 9 (µ 3 -pymS)(µ-H)] ( 2 ), while with [Os 3 (CO) 8 {µ 3 -Ph 2 PCH 2 P(Ph)C 6 H 4 }(μ-H)] leads to the isolation of only [Os 3 (CO) 8 (μ-pymS)(μ-H)(μ-dppm)] ( 3 ). In both reactions, the products are formed via incorporation of the thiolate part (pymS) of pymS‒SnPh 3 into the parent clusters through Sn‒S bond cleavage. Clusters 1 – 3 have been characterized by a combination of analytical and spectroscopic data together with single crystal X-ray diffraction analysis. Graphic Abstract Reactions of pymS‒SnPh 3 with two unsaturated triosmium clusters have been investigated which resulted in the isolation and characterization of three triosmium clusters containing a pymS ligand.