Details

Autor(en) / Beteiligte

• Xue, Ze‐Jian
• Li, Meng‐Yao
• Zhu, Bin‐Bin
• He, Zhi‐Tao
• Feng, Chen‐Guo
• Lin, Guo‐Qiang

Titel

A 1,4‐Palladium Migration/Heck Sequence with Unactivated Alkenes: Stereoselective Synthesis of Trisubstituted 1,3‐Dienes

Ist Teil von

• Advanced synthesis & catalysis, 2021-04, Vol.363 (8), p.2089-2092

Ort / Verlag

Heidelberg: Wiley Subscription Services, Inc

Erscheinungsjahr

2021

Quelle

Wiley Blackwell Single Titles

Beschreibungen/Notizen

• The palladium‐catalyzed cross‐coupling of ortho‐vinyl aromatic bromides and olefins was achieved through a controllable 1,4‐palladium migration/Heck cascade protocol. The reaction represents a mild, efficient and highly stereoselective method for the synthesis of trisubstituted 1,3‐dienes, especially for triaryl‐substituted ones.