Details

Autor(en) / Beteiligte

• Jin, Aihua
• Kim, Mi-Ju
• Lee, Kug-Seung
• Yu, Seung-Ho
• Sung, Yung-Eun

Titel

Spindle-like Fe7S8/N-doped carbon nanohybrids for high-performance sodium ion battery anodes

Ist Teil von

• Nano research, 2019-03, Vol.12 (3), p.695-700

Ort / Verlag

Beijing: Tsinghua University Press

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Iron sulfides have been considered as one of the most promising candidates for sodium ion battery anode materials due to their high theoretical capacity and low cost. In this work, spindle-like Fe 7 S 8 with nitrogen-doped carbon (Fe 7 S 8 /N-C) nanohybrids are successfully synthesized via a solvothermal method by sulfidation iron-based metal organic framework (FeMOF). As sodium ion battery anodes, Fe 7 S 8 /N-C nanohybrids exhibit high reversible capacity of 450.8 mAh·g −1 at 200 mA·g −1 , and 406.7 mAh·g −1 at 500 mA·g −1 even after 500 cycles. They also show excellent rate properties and delivering the capacity of 327.8 mAh·g −1 at a very high current density of 3.2 A·g −1 . These outstanding electrochemical performances can be attributed to the unique structure of Fe 7 S 8 /N-C nanohybrids. The nanoscale dimension in their size can be beneficial for facile ion and electron transports. Furthermore, the stable nitrogen doped carbon frameworks can also improve electrical conductivity and relieve the problems related to volume expansion. X-ray absorption spectroscopy and X-ray photoelectron spectroscopy analyses have been performed to study reactions occurred in spindle-like Fe 7 S 8 /N-C nanohybrid electrode at both bulk and surface.