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Current status of biomethane production using aqueous liquid from pyrolysis and hydrothermal liquefaction of sewage sludge and similar biomass
Ist Teil von
Reviews in environmental science and biotechnology, 2021-03, Vol.20 (1), p.237-255
Ort / Verlag
Dordrecht: Springer Netherlands
Erscheinungsjahr
2021
Link zum Volltext
Quelle
SpringerLink (Online service)
Beschreibungen/Notizen
Pyrolysis and hydrothermal liquefaction (HTL) are potential technologies for renewable energy production and waste valorization using municipal wastewater sewage sludge and other lignocellulosic biomass. However, the organic-rich aqueous pyrolysis liquid (APL) and HTL aqueous phase (HTL-AP) produced currently have no apparent use and are challenging to manage. Furthermore, the toxic organic compounds in them can be harmful to the environment. Anaerobic digestion (AD) may be a viable method to manage the liquids and recover energy in APL and HTL-AP in form of methane-rich biogas. Integrating thermochemical processes with AD could promote a circular economy by recovering resources and reducing environmental pollution. The challenge, however, is the presence of toxic compounds recalcitrant to anaerobic biodegradation such as phenols and nitrogen-containing organics that can inhibit methane-producing microbes. This review presents information on APL and HTL-AP characterization and biodegradability. Feedstock composition and process operational parameters are major factors affecting APL and HTL-AP composition, subsequent toxicity, and degradability. Feedstocks with high nitrogen content as well as increased thermochemical processing temperature and retention time result in a more toxic aqueous liquid and lower methane yield. Dilution and low AD organic loading are required to produce methane. More comprehensive APL and HTL-AP chemical characterization is needed to adopt suitable treatment strategies. Pretreatments such as overliming, air stripping, partial chemical oxidation, adsorption, and solvent extraction of toxic constituents as well as co-digestion and microbial acclimatization successfully reduce toxicity and increase methane yield.
Graphic abstract