Details

Autor(en) / Beteiligte

• Hu, Guang
• Kitney, Stuart P.
• Billa, Muralidhar Reddy
• Kelly, Stephen M.
• Lambert, Brian
• Harrison, William

Titel

A novel nematic tri-carbazole as a hole-transport material for solution-processed OLEDs

Ist Teil von

• Liquid crystals, 2021-01, Vol.48 (1), p.63-74

Ort / Verlag

Abingdon: Taylor & Francis

Erscheinungsjahr

2021

Quelle

Taylor & Francis Online

Beschreibungen/Notizen

• Two structural isomers of alkyl-substituted tri-carbazoles were synthesised to study the effect of the substitution pattern on their liquid crystalline behaviour and conductivity and performance in test OLEDs. The isomer with a 2,7-disubstitution pattern in the central carbazole exhibits a monotropic nematic phase, a high conductivity up to 10 Cd A −1 and is suitable as a hole-transport material for solution-processed OLEDs, achieving a high efficiency. The tri-carbazole isomer with a 3,6-substitution pattern, in the central carbazole, does not exhibit observable liquid crystalline behaviour, exhibits conductivity values two orders of magnitude lower than that of its 2,7-disubstituted isomer and performs poorly in OLEDs with the same configuration. Two structural isomers of alkyl-substituted tri-carbazoles A and B exhibit significantly different liquid crystalline behaviour, conductivity and performance in test OLEDs dependent upon their molecular shape.