Details

Autor(en) / Beteiligte

• Zhang, Rui
• Yuan, Yaoxin
• Zhang, Jianfeng
• Liu, Haiyun
• Chen, Gang
• Li, Kun
• Hong, MengQing
• Zuo, Wenbin
• Wang, Chunlan
• Yang, Wen
• Qin, Zhenxing

Titel

Improving the Mn2+ emission and stability of CsPb(Cl/Br)3 nanocrystals by Ni2+ doping in ambient air

Ist Teil von

• Journal of materials science, 2021-04, Vol.56 (12), p.7494-7507

Ort / Verlag

New York: Springer US

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Mn-doped perovskite CsPb(Cl/Br) 3 nanocrystals (NCs) have been widely explored due to their unique dual-color emission characteristics, which could reduce the usage of toxic Pb and introduce the exciton emission in blue region and the stable Mn 2+ emission peak in orange-red region via energy transfer from exciton to Mn 2+ emission. Although doping high concentration Mn 2+ could increase the Mn 2+ emission, excess Mn 2+ ions would be expelled from the host perovskite lattice. Doping secondary metal Ni into the NCs as an efficient method is always used to improve the Mn 2+ emission. We adopted a one-pot halogen injection into Cs-precursor under ambient environment method to prepare (Mn, Ni): CsPbCl 3 and (Mn, Ni): CsPb(Cl/Br) 3 NCs, which introduces NiCl 2 in the Mn: CsPb(Cl/Br) 3 NCs to supply enough halide ions and to passivate defect states or traps in the perovskite NCs so as to enhance Mn 2+ emission. Density Functional Theory (DFT) calculations were also conducted to explain our experimental results, which revealed that Ni 2+ doping could eliminate the in-gap deep defects of the CsPb(Cl/Br) 3 nanocrystals. In addition, the passivated lattice defects help to improve the stability of the perovskite NCs, preventing from electron beam irradiation.