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We present a direct mapping between the quantum optomechanical problem of the atoms harmonically trapped in the vicinity of a chiral waveguide and a generalized quantum Rabi model, and we discuss the analogy between the self-organization of atomic chains in photonic structures and Dicke-like quantum phase transitions in the ultrastrong coupling regime. We extend the class of the superradiant phase transitions for the systems possessing Z3 rather than parity Z2 symmetry and demonstrate the emergence of the multicomponent Schrödinger-cat ground states in these systems.