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STRUCTURE OF MIXED-LIGAND MAGNESIUM DIPIVALOYLMETHANATE COMPLEXES WITH PROPYLENEDIAMINE AND ITS DERIVATIVE
Ist Teil von
Journal of structural chemistry, 2020-09, Vol.61 (9), p.1405-1413
Ort / Verlag
Moscow: Pleiades Publishing
Erscheinungsjahr
2020
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The structures of two mixed-ligand [Mg(Q)(thd)
2
] complexes (thd = 2,2,6,6-tetramethylheptane-3,5-dionate ion (dipivaloylmethanate ion), Q = propane-1,3-diamine (pda), N,N,N′,N′-tetramethylpropane-1,3-diamine (tmpda)) are determined by X-ray crystallography. The structure of the complex with tmpda is determined at 296 K, that of the complex with pda is determined at 296 K and 150 K. Crystallographic data (296 K) for [Mg(pda)(thd)
2
]
I
are: space group
P
,
a
= 9.6363(3) Å,
b
= 12.1063(4) Å,
c
= 14.3401(5) Å, α = 70.6430(10)°, β = 72.7680(10)°, γ = 89.376(2)°,
V
= 1500.41(9) Å
3
,
Z
= 2. Crystallographic data for [Mg(tmpda)(thd)
2
]
II
are: space group
С
2/
с
,
a
= 10.3716(3) Å,
b
= 17.3614(4) Å,
c
= 19.1577(5) Å, β = 90.8480(10)°,
V
= 3449.26(16) Å
3
,
Z
= 6. Crystal packings are formed by mononuclear molecules that are organized in dimers by N–H…O hydrogen bonds in the structure of
I
. Magnesium atoms have a distorted octahedral coordination environment. In
I
and
II
molecules, Mg–O bond lengths are comparable and vary in ranges 2.027-2.062 Å and 2.023-2.030 Å respectively; OMgO chelate angles are close to 86°. In complex
II
, Mg–N bond lengths and the NMgN angle are remarkably larger than those in
I
: 2.331
vs
. 2.193-2.229 Å; 89.6
vs
. 84.7°. A comparative analysis of molecular structures and crystal packings of related [Mg(Q)(thd)
2
] complexes with diamines of propylene and ethylene series is carried out.