Details

Autor(en) / Beteiligte

• Schröder, Philipp
• Aguiló-Aguayo, Noemí
• Auer, Andrea
• Grießer, Christoph
• Kunze-Liebhäuser, Julia
• Ma, Yibo
• Hummel, Michael
• Obendorf, Dagmar
• Bechtold, Thomas

Titel

Activation of carbon tow electrodes for use in iron aqueous redox systems for electrochemical applications

Ist Teil von

• Journal of materials chemistry. C, Materials for optical and electronic devices, 2020-06, Vol.8 (23), p.7755-7764

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2020

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Excellent chemical inertness, good conductivity and high overpotentials for water electrolysis make carbon fibres (CFs) an ideal electrode material for electrochemical applications. A customized design of three-dimensional (3D) carbon electrodes can be achieved by tailored fibre placement of carbon tows with textile production techniques like embroidery. After manufacturing of the 3D structure, appropriate removal of the polymer coating and oxidative activation is required to achieve low overpotentials and avoid thermal treatments of the carbon structure. For the electrolytes Na[Fe III -racEDDHA] and K 4 [Fe II (CN) 6 ] a sequential treatment by acetone extraction and anodic oxidation was identified to yield optimum surface activation. Electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy of activated fibres indicated complete removal of the coating layer without damage of the CFs. From electrochemical impedance spectroscopy (EIS) at the carbon tow electrodes, charge transfer resistances of <0.1 Ω (0.023 Ω g) and < 0.2 Ω (0.046 Ω g) were determined at 50% state-of-charge (SoC) for 65 mM K 4 [Fe II (CN) 6 ] and 65 mM Na[Fe III -racEDDHA], respectively. In potentiostatic bulk electrolysis no electrode deactivation was observed during 10 charge/discharge cycles (5-6 hours) between 10% and 90% SoC. The processing of carbon tows by textile techniques to near net shaped 3D electrodes opens a new method to manufacture electrodes for electrochemical applications, such as redox flow cells. Activation of technical carbon tow opens access to new electrode material and electrode design for all iron redox flow cells.