Details

Autor(en) / Beteiligte

• Zhang, Bentian
• Fu, Gengtao
• Li, Yutao
• Liang, Lecheng
• Grundish, Nicholas S.
• Tang, Yawen
• Goodenough, John B.
• Cui, Zhiming

Titel

General Strategy for Synthesis of Ordered Pt3M Intermetallics with Ultrasmall Particle Size

Ist Teil von

• Angewandte Chemie (International ed.), 2020-05, Vol.59 (20), p.7857-7863

Auflage

International ed. in English

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2020

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Controllable synthesis of atomically ordered intermetallic nanoparticles (NPs) is crucial to obtain superior electrocatalytic performance for fuel cell reactions, but still remains arduous. Herein, we demonstrate a novel and general hydrogel‐freeze drying strategy for the synthesis of reduced graphene oxide (rGO) supported Pt3M (M=Mn, Cr, Fe, Co, etc.) intermetallic NPs (Pt3M/rGO‐HF) with ultrasmall particle size (about 3 nm) and dramatic monodispersity. The formation of hydrogel prevents the aggregation of graphene oxide and significantly promotes their excellent dispersion, while a freeze‐drying can retain the hydrogel derived three‐dimensionally (3D) porous structure and immobilize the metal precursors with defined atomic ratio on GO support during solvent sublimation, which is not afforded by traditional oven drying. The subsequent annealing process produces rGO supported ultrasmall ordered Pt3M intermetallic NPs (≈3 nm) due to confinement effect of 3D porous structure. Such Pt3M intermetallic NPs exhibit the smallest particle size among the reported ordered Pt‐based intermetallic catalysts. A detailed study of the synthesis of ordered intermetallic Pt3Mn/rGO catalyst is provided as an example of a generally applicable method. This study provides an economical and scalable route for the controlled synthesis of Pt‐based intermetallic catalysts, which can pave a way for the commercialization of fuel cell technologies. A novel and general strategy for the synthesis of reduced graphene oxide (rGO) supported atomically ordered Pt3M (M=Mn, Cr, Fe, Co, etc.) intermetallic nanoparticles is reported under the aid of freeze‐drying technology. This synthetic strategy is demonstrated to be effective for the preparation and handling of nanoparticles with controlled particle size and ordered phase.