Details

Autor(en) / Beteiligte

• Jayawardena, K. D. G. I
• Bandara, R. M. I
• Monti, M
• Butler-Caddle, E
• Pichler, T
• Shiozawa, H
• Wang, Z
• Jenatsch, S
• Hinder, S. J
• Masteghin, M. G
• Patel, M
• Thirimanne, H. M
• Zhang, W
• Sporea, R. A
• Lloyd-Hughes, J
• Silva, S. R. P

Titel

Approaching the Shockley-Queisser limit for fill factors in lead-tin mixed perovskite photovoltaics

Ist Teil von

• Journal of materials chemistry. A, Materials for energy and sustainability, 2020, Vol.8 (2), p.693-75

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2020

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The performance of all solar cells is dictated by charge recombination. A closer to ideal recombination dynamics results in improved performances, with fill factors approaching the limits based on Shockley-Queisser analysis. It is well known that for emerging solar materials such as perovskites, there are several challenges that need to be overcome to achieve high fill factors, particularly for large area lead-tin mixed perovskite solar cells. Here we demonstrate a strategy towards achieving fill factors above 80% through post-treatment of a lead-tin mixed perovskite absorber with guanidinium bromide for devices with an active area of 0.43 cm 2 . This bromide post-treatment results in a more favorable band alignment at the anode and cathode interfaces, enabling better bipolar extraction. The resulting devices demonstrate an exceptional fill factor of 83%, approaching the Shockley-Queisser limit, resulting in a power conversion efficiency of 14.4% for large area devices. A new post-treatment method for lead-tin mixed perovskites enabling device fill factors approaching 83%.