Details

Autor(en) / Beteiligte

• Nimax, Patrick R
• Zoller, Florian
• Blockhaus, Tobias
• Küblböck, Teresa
• Fattakhova-Rohlfing, Dina
• Sünkel, Karlheinz

Titel

An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

Ist Teil von

• New journal of chemistry, 2020, Vol.44 (1), p.72-78

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2020

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl 2 with Ag[C 5 (CN) 4 (NH 2 )] and recrystallization in MeOH, performed in sunlight. The radical was characterized by X-ray diffraction, EPR and UV Vis spectroscopy as well as by cyclovoltammetry and DFT calculations. Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl 2 with Ag[C 5 (CN) 4 (NH 2 )] and recrystallization in MeOH was performed in sunlight.