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A multi-stimuli-responsive metallohydrogel applied in chiral recognition, adsorption of poisonous anions, and construction of various chiral metal-organic frameworks
Ist Teil von
Chemical communications (Cambridge, England), 2019, Vol.55 (94), p.14178-14181
Ort / Verlag
Cambridge: Royal Society of Chemistry
Erscheinungsjahr
2019
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The design of stimuli-responsive hydrogels is attractive but challenging. A multi-stimuli-responsive chiral metallohydrogel was constructed using a rational approach to design a functional metallohydrogel using chiral organic gelators. The as-synthesized metallohydrogel reported here performed remarkably as a visual sensor for discriminating between (
R
)-phenylglycinol and (
S
)-phenylglycinol. Furthermore, the metallohydrogel showed a significant capacity for adsorption and enrichment of Cr(
vi
) in aqueous solution. Besides this, by utilizing anion-induced transformation, the metallohydrogel could be controllably directed to synthesize different types of chiral metal-organic frameworks.
A multi-stimuli-responsive chiral metallohydrogel applied to chiral recognition, adsorption of poisonous anions, and construction of various chiral metal-organic frameworks.