Details

Autor(en) / Beteiligte

• Xu, Xuebin
• Xiao, Jiannan
• Liu, Meiying
• Liu, Zhiliang

Titel

A multi-stimuli-responsive metallohydrogel applied in chiral recognition, adsorption of poisonous anions, and construction of various chiral metal-organic frameworks

Ist Teil von

• Chemical communications (Cambridge, England), 2019, Vol.55 (94), p.14178-14181

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The design of stimuli-responsive hydrogels is attractive but challenging. A multi-stimuli-responsive chiral metallohydrogel was constructed using a rational approach to design a functional metallohydrogel using chiral organic gelators. The as-synthesized metallohydrogel reported here performed remarkably as a visual sensor for discriminating between ( R )-phenylglycinol and ( S )-phenylglycinol. Furthermore, the metallohydrogel showed a significant capacity for adsorption and enrichment of Cr( vi ) in aqueous solution. Besides this, by utilizing anion-induced transformation, the metallohydrogel could be controllably directed to synthesize different types of chiral metal-organic frameworks. A multi-stimuli-responsive chiral metallohydrogel applied to chiral recognition, adsorption of poisonous anions, and construction of various chiral metal-organic frameworks.