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Details

Autor(en) / Beteiligte
Titel
Magnetic iron oxide modified MIL-101 composite as an efficient visible-light-driven photocatalyst for methylene blue degradation
Ist Teil von
  • Journal of porous materials, 2019-12, Vol.26 (6), p.1699-1712
Ort / Verlag
New York: Springer US
Erscheinungsjahr
2019
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
  • In this study, a facile hydrothermal method was used to prepare Fe 3 O 4 /MIL-101 composite as a photocatalyst. The resulting composite was characterized using X-ray diffraction, scanning electron microscopy, nitrogen adsorption/desorption isotherms, thermal analysis, X-ray photoelectron spectroscopy, and UV–Vis diffuse reflection spectroscopy. The Fe 3 O 4 /MIL-101 composite possesses a large surface area and mesoporous structure and exhibits a good photocatalytic activity for the MB degradation in the visible light region. A kinetic model for dye degradation over this heterogeneous catalyst was proposed by combining the parameters of the Langmuir isotherms and the kinetics of the unimolecular reaction. The proposed model fixes well with the experimental data. The mechanism of MB photocatalytic degradation is also addressed. The catalyst is stable after three recycles, which makes it a potential candidate for environmental restoration.

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