Details

Autor(en) / Beteiligte

• Serkova, Olga S.
• Kamkina, Anastasia V.
• Sivkova, Anastasia S.
• Maslennikova, Vera I.

Titel

Synthesis of oligophosphonate aromatic systems using the Michaelis-Arbuzov reaction and microwave radiation

Ist Teil von

• Phosphorus, sulfur, and silicon and the related elements, 2019-11, Vol.194 (11), p.1082-1089

Ort / Verlag

Abingdon: Taylor & Francis

Erscheinungsjahr

2019

Quelle

Taylor & Francis Journals

Beschreibungen/Notizen

• The microwave-assisted Michaelis-Arbuzov reaction of 2-aryloxy-1,3,2-dioxaphosphinanes was investigated. The dioxaphosphinane groups immobilized on dinaphthylmethane or resorcinarene core react with alkyl/arylalkyl halides/bromoethyl acetate with opening of the phosphinane ring to give linear unsymmetrical phosphonates. The number and spatial orientation of the resulting phosphonate groups depend on the structure and topology of the aromatic substrate and the nature of the alkylating reagent.