Details

Autor(en) / Beteiligte

• Royuela, Sergio
• Almarza, Joaquín
• Mancheño, María J.
• Pérez‐Flores, Juan C.
• Michel, Enrique G.
• Ramos, María M.
• Zamora, Félix
• Ocón, Pilar
• Segura, José L.

Titel

Synergistic Effect of Covalent Bonding and Physical Encapsulation of Sulfur in the Pores of a Microporous COF to Improve Cycling Performance in Li‐S Batteries

Ist Teil von

• Chemistry : a European journal, 2019-09, Vol.25 (53), p.12394-12404

Ort / Verlag

Germany: Wiley Subscription Services, Inc

Erscheinungsjahr

2019

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• Lithium‐sulfur batteries stands out as a promising technology for energy storage owing to a combination of favorable characteristics including a high theoretical gravimetric capacity, energy density, inexpensive character, and environmental benignity. Covalent organic frameworks (COFs) are a rapidly developing family of functional nanostructures which combine porosity and crystallinity, and which have been already used in these kinds of batteries to build sulfur electrodes, by embedding sulfur into porous COFs in order to enhance cycle lifetimes. In this contribution, this is taken one step forward and a COF endowed with vinyl groups is used, in order to graft sulfur to the COF skeleton through inverse vulcanization. The main aim of the article is to show the synergistic effect of covalent bonding and physical encapsulation of sulfur in the pores of the COF in order to alleviate the fatal redox shuttling process, to improve the cycling performance, and to provide faster ion diffusion pathways. In addition, it is shown how the material with covalently‐bound S provides better electrochemical performance under demanding and/or changeable charge conditions than a parent analogue material with sulfur physically confined, but without covalent linkage. COF it up: Synergistic effect of covalent bonding and physical encapsulation of sulfur in the pores of a COF alleviates the fatal redox shuttling process, improves the cycling performance and provides faster ion diffusion pathways in lithium‐sulfur batteries.