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A reliable and low‐cost solution‐processing procedure to synthesize a highly adhesive flexible metal antenna with low resistivity for radio‐frequency identification device (RFID) tags on paper substrates via inkjet printing combined with surface modification and electroless deposition (ELD) is demonstrated in this paper. Through the surface modification of colloidal solution of hydrolyzed stannous chloride and chitosan solution, the paper‐based substrate is able to reduce the penetration rate of ink and further increase the adsorption amount of silver ions, which could create a catalytic activating layer to catalyze the subsequent ELD of a conductive deposited metal antenna. The resulting metal antenna for RFID tags presents good adhesive strength and low resistivity of 2.58 × 10−8 Ω·m after 40 min of ELD, and maintains a reliable reading range of RFID tags even after over 1000 times of bending and mechanical stress. Consequently, the developed technology proposed allows for cheap, efficient, and massive production of metal antenna for paper‐based RFID tags with excellent mechanical and electrical properties. Furthermore, this process is especially advantageous for the fabrication of next‐generation flexible electronic devices based on paper substrates.
A novel and efficient solution‐processing procedure combined with inkjet printing, surface modification, and electroless deposition is proposed for the fabrication of an outstanding flexible radio‐frequency identification device (RFID) tag metal antenna on a paper‐based substrate without high temperature or sophisticated manufacturing equipment. This method is a low‐cost and portable fabrication route for RFID antennas, which is promising for large‐scale commercial manufacturing.