Catalysis letters, 2011-05, Vol.141 (5), p.735-741
2011
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Details
- Autor(en) / Beteiligte
- Titel
- A One-Pot Two-Step Approach for the Catalytic Conversion of Glucose into 2,5-Diformylfuran
- Ist Teil von
- Catalysis letters, 2011-05, Vol.141 (5), p.735-741
- Ort / Verlag
- Boston: Springer US
- Erscheinungsjahr
- 2011
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- One-pot two-step synthesis of DFF was achieved by catalytic conversion of glucose over CrCl 3 ·6H 2 O/NaBr//NaVO 3 ·2H 2 O catalysts, and a DFF yield of 55% based on glucose was obtained. This glucose conversion process is characterized by the abundance and low cost of starting material and no need for HMF separation or purification. Graphical Abstract An alternative one-pot one-step approach for the catalytic conversion of glucose into DFF with a yield of 18% in the CrCl 3 ·6H 2 O/NaBr//NaVO 3 ·2H 2 O system has been reported for the first time. Two-step process can give higher DFF yield than one-step, and the best DFF yield of 55% can be obtained under mild reaction conditions.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1011-372XeISSN: 1572-879XDOI: 10.1007/s10562-011-0555-9Titel-ID: cdi_proquest_journals_2258925907
- Format
- –
- Schlagworte
- Catalysis, Catalytic converters, Chemical synthesis, Chemistry, Chemistry and Materials Science, Conversion, Dextrose, Exact sciences and technology, General and physical chemistry, Glucose, Glucose metabolism, Industrial Chemistry/Chemical Engineering, Organometallic Chemistry, Physical Chemistry, Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry