Catalysis letters, 2013-02, Vol.143 (2), p.142-149
2013
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Details
- Autor(en) / Beteiligte
- Titel
- Regioselective Hydrogenation of 1,2-Indanedione Over Heterogeneous Pd and Pt Catalysts
- Ist Teil von
- Catalysis letters, 2013-02, Vol.143 (2), p.142-149
- Ort / Verlag
- Boston: Springer US
- Erscheinungsjahr
- 2013
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Regioselective hydrogenation of 1,2-indanedione yielding rac -2-hydroxy-1-indanone was investigated using heterogeneous Pt and Pd as catalysts. Five consecutive experiments were carried out for studying the performance of Pd/Al 2 O 3 . Practical operation under atmospheric pressure of hydrogen at low temperature (40 °C) for 120 min gave the desired product in >99 % regioselectivity, 84 % conversion and 77 % yield, according to GC, using 2 mol% Pd/Al 2 O 3 as the catalyst. Graphical Abstract
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1011-372XeISSN: 1572-879XDOI: 10.1007/s10562-012-0951-9Titel-ID: cdi_proquest_journals_2258925324
- Format
- –
- Schlagworte
- Aluminum oxide, Catalysis, Catalysts, Chemistry, Chemistry and Materials Science, Enantiomers, Exact sciences and technology, General and physical chemistry, Heterogeneous catalysis, Hydrogen, Hydrogen storage, Hydrogenation, Industrial Chemistry/Chemical Engineering, Organometallic Chemistry, Palladium, Palladium catalysts, Physical Chemistry, Platinum, Regioselectivity, Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry