Details

Autor(en) / Beteiligte

• Batey, Robert A.
• Quach, Tan D.
• Shen, Ming
• Thadani, Avinash N.
• Smil, David V.
• Li, Sze-Wan
• MacKay, D. Bruce

Titel

Organoboron compounds as mild nucleophiles in Lewis acid- and transition metal-catalyzed C­C bond-forming reactions

Ist Teil von

• Pure and applied chemistry, 2002-01, Vol.74 (1), p.43-55

Ort / Verlag

Berlin: De Gruyter

Erscheinungsjahr

2002

Link zum Volltext

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• The use of air- and water-stable organoboron compounds for C­C bond-forming reactions are reported. These studies include the Lewis acid-promoted additions of boronic esters to N-acyliminium ions and allyl and crotyltrifluoroborate salts to aldehydes. Aryl and alkenyltrifluoroborate salts will add to aldehydes under the influence of rhodium catalysis or in the presence of zinc metal. These salts also participate in palladium-catalyzed Suzuki­Miyaura and other cross-coupling reactions. Finally, a new type of N-heterocyclic carbene ligand is reported and used for Pd-catalyzed Suzuki­Miyaura couplings.