Details

Autor(en) / Beteiligte

• Ranu, Brindaban C.
• Chattopadhyay, Kalicharan
• Adak, Laksmikanta
• Saha, Amit
• Bhadra, Sukalyan
• Dey, Raju
• Saha, Debasree

Titel

Metal nanoparticles as efficient catalysts for organic reactions

Ist Teil von

• Pure and applied chemistry, 2009-11, Vol.81 (12), p.2337-2354

Ort / Verlag

Berlin: De Gruyter

Erscheinungsjahr

2009

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• Pd(0) nanoparticles have been demonstrated to be very efficient catalysts for C–C bond-forming reactions. These include coupling of -diiodoalkenes and acrylic esters and nitriles leading to the stereoselective synthesis of 2-alkene-4-yn-esters and nitriles, allylation of active methylene compounds by allyl acetate, and Hiyama cross-coupling of aryliodides with arylsilanes. Cu(0) nanoparticles catalyze aryl-sulfur bond formation, accomplishing the synthesis of functionalized aryl sulfides and aryl- and vinyl dithiocarbamates. Cu nanoparticles have also been used for the chemoselective reduction of aromatic nitro compounds.