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Besides designing channel-hopping (CH) sequences, finding good methods of communication rendezvous is important for improving spectral efficiency and alleviating traffic load of cognitive radio (CR) networks. In this paper, new asynchronous-symmetric CH sequences are constructed and their (channel overlap, even-channel-use, and pairwise shift invariance) properties are investigated. Their operations in three transmission scenarios involving different basic collision-avoidance mechanisms are analyzed and compared in terms of maximum time-to-rendezvous, rendezvous-success (RS) rate, and RS variance. This paper shows that the new sequences have shorter period, larger cardinality, and smaller RS variations than other CH sequences, thus supporting greater number of secondary users and more frequent and uniform rendezvous in the CR networks.