Details

Autor(en) / Beteiligte

• Postigo, Al

Titel

Electron Donor‐Acceptor Complexes in Perfluoroalkylation Reactions

Ist Teil von

• European journal of organic chemistry, 2018-12, Vol.2018 (46), p.6391-6404

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Electron‐donor‐acceptor complexes (EDA) can be established through halogen‐bonding interactions between the N lone electron pair from organic bases (or N‐/O‐centered anions) and perfluoroalkyl iodides RF–I. These EDA complexes can be activated thermally or photochemically, and will be shown to be responsible for new C–RF bond formation reactions, bypassing the use of visible‐light photocatalysts (either organic or organometallic) or harsh reaction conditions, thus simplifying reaction protocols, work‐up and analysis. Through this strategy, diverse reaction types can be realized, such as atom transfer radical additions, homolytic aromatic substitutions, and multicomponent reactions. Visible light photoactive EDA complexes facilitate the production of perfluoroalkyl radicals RF without the need for external photocatalysts