Details

Autor(en) / Beteiligte

• Chen, Qian
• Wang, Xiaofeng
• Yu, Guodian
• Wen, Chunxiao
• Huo, Yanping

Titel

DDQ-mediated direct C(sp3)–H phosphorylation of xanthene derivatives

Ist Teil von

• Organic chemistry frontiers an international journal of organic chemistry, 2018-09, Vol.5 (18), p.2652-2656

Ort / Verlag

London: Royal Society of Chemistry

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A convenient and efficient C(sp3)–H phosphorylation has been achieved via the metal-free DDQ-mediated cross-dehydrogenative coupling between diarylphosphine oxides and xanthene derivatives at room temperature. This transformation provides a direct synthetic route to the construction of C(sp3)–P bonds with good functional group compatibility, leading to the formation of alkylphosphonates in up to 96% yield.