Details

Autor(en) / Beteiligte

• Wang, Yuan
• Arandiyan, Hamidreza
• Liu, Yuxi
• Liang, Yijing
• Peng, Yue
• Bartlett, Stuart
• Dai, Hongxing
• Rostamnia, Sadegh
• Li, Junhua

Titel

Template‐free Scalable Synthesis of Flower‐like Co3‐xMnxO4 Spinel Catalysts for Toluene Oxidation

Ist Teil von

• ChemCatChem, 2018-08, Vol.10 (16), p.3429-3434

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2018

Quelle

Wiley Online Library

Beschreibungen/Notizen

• The rational design of low‐cost transition metal catalysts that exhibit high activity and selectivity may be the most significantly investigated in heterogeneous catalysis. In this study, Co3‐xMnxO4 (x=0.75, 1.0, and 1.5) mixed metal oxides were successfully synthesized by a controlled template‐free autoclave strategy and studied for toluene oxidation. It is found that the Co‐rich sample showed markedly enhanced activity and the 3D dandelion‐like Co2.25Mn0.75O4 catalyst exhibited in the highest toluene oxidation rate (8.9 μmol/(gcats)) and a 100 % toluene conversion at 239 °C. In situ DRIFTS study indicates that toluene was sequentially oxidized to benzyl radical, benzaldehyde, benzene, oxalic acid, and finally to CO2 and H2O. The interaction between Co and Mn, in conjunction with the high concentration of surface oxygen species and rich surface oxygen vacancies, reasonably explains the elevated catalytic activity and thermal stability for toluene oxidation over 3D flower‐like Co3‐xMnxO4 spinel catalysts. In full blossom: Flower‐like spinel Co−Mn solid solution are self‐assembled using the template‐free strategy. The low‐cost transition metal‐based catalysts are active for toluene oxidation. High adsorbed oxygen species enhance catalytic performance.