Details

Autor(en) / Beteiligte

• Sun, S.-W.
• Wang, G.-F.

Titel

Structural Characterization of a Cu(I)/Br Complex with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands

Ist Teil von

• Journal of structural chemistry, 2018-05, Vol.59 (3), p.744-747

Ort / Verlag

Moscow: Pleiades Publishing

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The synthesis of a novel Cu(I) complex with V-shaped bidentate ligands {[Cu(BIPMO)]×[CuBr 2 ]} n where BIPMO = bis(4-(1 H -imidazol-1-yl)phenyl)methanone is reported. It is characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. Copper(I) ions in the complex are in a distorted environment in which donor atoms are provided by the bromide anion and nitrogen atoms of BIPMO ligands, respectively. Infinite anion chains formed by CuX 4 (X = Br or N) polyhedra are linked by BIPMO ligands to give rise to layers. Furthermore, the layers are linked into 3D networks through weak intermolecular interactions.