Details

Autor(en) / Beteiligte

• Mochizuki, Jumpei
• Horikoshi, Seira
• Oya, Yasuhisa
• Chikada, Takumi

Titel

Deuterium permeation behavior of tritium permeation barrier coating containing carbide nanoparticles

Ist Teil von

• Fusion engineering and design, 2017-11, Vol.124, p.1073-1076

Ort / Verlag

Amsterdam: Elsevier B.V

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• •Y2O3 coatings with carbide nanoparticles were fabricated by metal organic decomposition.•Deuterium permeation through Y2O3 coatings containing carbide nanoparticles was examined.•The permeability varied by fabrication process with and without pretreatment.•The coatings showed approximately 1000 times lower permeability than uncoated substrate.•Agglomerated nanoparticles in the liquid precursor led to peeling after heat treatment. Y2O3 coatings containing Cr3C2 nanoparticles have been prepared on reduced activation ferritic/martensitic steel F82H substrates by metal organic decomposition with dip-coating technique, and their deuterium permeation behaviors have been investigated. The surface condition of the samples varied with pre-treatment process: fabrication of Y2O3 coatings without the Cr3C2 nanoparticles or surface oxidation of F82H. In the coating without pre-treatment, peeling of agglomerated nanoparticles and oxidation of the substrate at the peeled regions were observed. Pores were also observed in the coatings with pre-treatment; however, iron oxide was not formed. The deuterium permeation flux of the coating fabricated without pre-treatment was lower than that of uncoated F82H substrate by a factor of 100 even after crystallization at 700°C. In the case of the sample with pre-treatment, the permeation flux was by a factor of 100 lower than that of uncoated substrate before crystallization, and the factor increased to approximately 1000 after crystallization. Dispersion of the nanoparticles and securement of surface coverage of the coating are key factors to establish high-performance tritium permeation barrier.