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A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery
Ist Teil von
Energy & environmental science, 2018-01, Vol.11 (5), p.1197-1203
Ort / Verlag
Cambridge: Royal Society of Chemistry
Erscheinungsjahr
2018
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
In this article, we demonstrated for the first time an ultra-strong bacterial cellulose supported poly(methyl vinyl ether-
alt
-maleic anhydride) as a multifunctional polymer electrolyte for a 4.45 V-class LiCoO
2
lithium metal battery. Such a polymer electrolyte based LiCoO
2
lithium metal battery delivered significant capacity retention (85% retention after 700 cycles) at 60 °C. A more thorough investigation elucidated that it played multiple roles in enhancing the electro-oxidative resistance and reversible lithium plating/stripping of a LiCoO
2
lithium metal cell. These extraordinary features open up a new avenue for the fabrication of advanced polymer electrolytes for high-voltage lithium metal cells.